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An efficient metal-free reduction using diphenylsilane with (tris–perfluorophenyl)borane as catalyst
Journal article   Peer reviewed

An efficient metal-free reduction using diphenylsilane with (tris–perfluorophenyl)borane as catalyst

MeiXuan Tan, Yugen Zhang and Mei Xuan Tan
Tetrahedron letters, Vol.50(34), pp.4912-4915
26/08/2009

Abstract

An efficient metal-free reduction of various C X (X = O, N, C) bonds into their corresponding amines or hydrocarbons using the Ph 2SiH 2/B(C 6F 5) 3 catalytic system is demonstrated. This protocol reduces enamines, enol esters, carbonyls, amides, and isocyanates. An efficient metal-free reduction of various C X (X = O, N, C) bonds to their corresponding amines or hydrocarbons using the Ph 2SiH 2/B(C 6F 5) 3 catalytic system is demonstrated. This protocol reduces enamines, enol esters, carbonyls, amides, and isocyanates.

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