Logo image
Effect of Iron Concentration and Annealing Conditions on the Catalytic Performance of Co-Mn Spinel Oxides with a Unique Nanowire-Nanosheet Coexisting Structure for Water Oxidation
Journal article   Peer reviewed

Effect of Iron Concentration and Annealing Conditions on the Catalytic Performance of Co-Mn Spinel Oxides with a Unique Nanowire-Nanosheet Coexisting Structure for Water Oxidation

Xue Li, Komal Patil, Pravin Babar, Ashutosh Agarwal, Xing Chen, Dong Myeong Kim, Jin Hyeok Kim and Yung Tae Yoo
Energy & fuels, Vol.36(14), pp.7806-7815
21/07/2022

Abstract

Energy & Fuels Engineering Engineering, Chemical Science & Technology Technology
In this work, cobalt-manganese-iron trimetallic oxide (CoMnFeO4) with a unique nanowire-nanosheet coexisting structure was synthesized by a hydrothermal method, followed by calcination. It is worth mentioning that the optimal iron concentration was 1.5 mmol and the suitable calcination temperature was 300 degrees C for 1 h in the Ar atmosphere. The as-prepared CoMnFeO4 showed outstanding oxygen evolution reaction (OER) performance in an alkaline medium with low overpotentials of 242 and 331 mV at a Tafel slope of 102 mv dec(-1) to deliver current densities of 10 and 50 mA cm(-2). The enhanced OER performance can be ascribed to the intrinsic electrocatalytic activity, which resulted from the porous nickel foam substrate, excellent structural stability, and the synergetic effect of multications in the trimetallic catalyst, low solution resistance, fast electron transportation, and efficiently exposed active sites.

Metrics

1 Record Views

Details

Logo image