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Influence of Ce and Co doping ions on photorefractive effect of SBN:61 crystals
Journal article   Peer reviewed

Influence of Ce and Co doping ions on photorefractive effect of SBN:61 crystals

Minghua Li, Xuewu Xu, Dongxiao Qiu, Towchong Chong, Hirohiko Kumagai and Masahiro Hirano
Journal of crystal growth, Vol.211(1), pp.225-229
01/04/2000

Abstract

Absorption spectra Photorefractive doped SBN crystals Two-beam coupling X-ray diffraction
Ce-, Co-, and (Ce,Co)-doped Sr 0.61Ba 0.39Nb 2O 6 (SBN:61) crystals with different concentrations were grown by Czochralski technique in the congruent composition. It is the first report of double-doped SBN crystals with Ce and Co. The doping ions Ce and Co occupy 15- (or 12-) fold coordinated and 6-fold coordinated lattice sites in crystal, respectively. A little change of the lattice constants induced by doping ions were detected by XRD experiments. Absorption spectra show that Ce 3+ and Co 3+ are dominant valence status in SBN:61 crystal. Ce and Co doping enhances two-beam coupling gain coefficient and photorefractive response speed, due to these doping ions donating or capturing electrons during the photorefractive process.

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