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Noncovalent Functionalization of Boron Nitride Nanotubes with Poly(p-phenylene-ethynylene)s and Polythiophene
Journal article   Peer reviewed

Noncovalent Functionalization of Boron Nitride Nanotubes with Poly(p-phenylene-ethynylene)s and Polythiophene

Singaravelu Velayudham, Chee Huei Lee, Ming Xie, Dominique Blair, Nicholas Bauman, Yoke Khin Yap, Sarah A. Green and Haiying Liu
ACS applied materials & interfaces, Vol.2(1), pp.104-110
27/01/2010
PMID: 20356226

Abstract

Materials Science Materials Science, Multidisciplinary Nanoscience & Nanotechnology Science & Technology Science & Technology - Other Topics Technology
Boron nitride nanotubes (BNNTs) are functionalized and solubilized in organic solvents such as chloroform, methylene chloride, and tetrahydrofuran by using conjugated poly(p-phenylene ethynylene)s (PPEs) (polymers A and B) and polythiophene (polymer C) via a noncovalent functionalization approach through strong pi-pi stacking interactions between the conjugated polymers and BNNTs. The functionalization of BNNTs with PPEs enhanced planarization of PPEs with red shifts in both absorbance and emission of the composite materials with reference to free PPEs, whereas the functionalization of BNNTs with polythiophene disrupts the pi-conjugation, resulting in blue shifts in both the absorption and emission of the composite material.

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