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Oscillation in Penetration Distance in a Train of Chemical Pulses Propagating in an Optically Constrained Narrowing Channel
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Oscillation in Penetration Distance in a Train of Chemical Pulses Propagating in an Optically Constrained Narrowing Channel

Hiroyuki Kitahata, Kenji Fujio, Jerzy Gorecki, Satoshi Nakata, Yasuhiro Igarashi, Agnieszka Gorecka and Kenichi Yoshikawa
The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, Vol.113(39), pp.10405-10409
01/10/2009
PMID: 19731900

Abstract

Chemistry Chemistry, Physical Physical Sciences Physics Physics, Atomic, Molecular & Chemical Science & Technology
A chemical wave train propagating in a narrowing excitable channel surrounded by a nonexcitable field is investigated by using a photosensitive Belousov-Zhabotinsky (BZ) reaction. The considered geometry is created as a dark triangle surrounded by an illuminated area where the reaction is suppressed by the light-induced generation of bromide ion. For a low illumination level, a pulse train terminates at a constant position. However, as the light intensity increases, the position at which subsequent pulses disappear changes periodically, so that the period-doubling of penetration depth occurs. Two-dimensional simulations based on a modified Oregonator model for the photosensitive BZ reaction reproduce the essential features of the experimental observation.

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