Abstract
Tuning the color of Au has been a longstanding problem in the luxury industry. Conventional approaches, involving Au alloying, compromise purity and demand distinct alloy compositions for each hue. This study demonstrates a lithography-free method for generating structural colors on a gold surface by adjusting the thickness of titanium dioxide, a high-index dielectric. While color tuneability is limited if TiO2 is coated directly on the Au surface, a range of vivid colors can be generated if a 50-100 nm thick AuAl2 underlayer is used. AuAl2, an accepted alloy for purple gold, broadens the color gamut, providing a protective coating without diminishing gold purity. The reflectance dip of the bilayer structure exhibits a significant red shift with increasing thickness of the TiO2 layer, allowing diverse colors by TiO2 insulator tuning. Simulation studies corroborate experimental results, affirming that coating a TiO2 layer on the AuAl2 underlayer yields a wide range of colors. This method, based on thin-film interference, shows promise for widespread use, offering a broad spectrum of structural colors in an industry striving for diverse Au color representation.
This study addresses the longstanding challenge in the luxury industry for gold coloration. Using a lithography-free approach, it showcases diverse structural colors on gold surfaces by varying titanium dioxide (TiO2) thickness. Incorporating a 50-100 nm thick AuAl2 underlayer expands color possibilities without compromising purity. This method, based on thin-film interference, holds promise for diverse and customizable gold surface coloration.image (c) 2024 WILEY-VCH GmbH